Bis[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II) dichloride methanol disolvate dihydrate
نویسندگان
چکیده
In the title compound, [Cu(C(16)H(14)N(5))(2)]Cl(2)·2CH(4)O·2H(2)O, the cationic metal complex resides on a crystallographic centre of inversion, with the Cu(2+) bonded to two bis-(1H-benzimidazol-2-ylmeth-yl)amines (IDB). The coordination geometry of the Cu(2+) ion is distorted octa-hedral with an N(6) ligand set. A three-dimensional framework structure is formed by means of hydrogen bonds and π-π inter-actions formed between imidazole and phenyl rings, and between phenyl and phenyl rings, with centroid-to-centroid distances of 3.690 (2)-3.977 (2) Å and interplanar spacings of 3.445 (2)-3.502 (2) Å.
منابع مشابه
Bis[2,6-bis(1-methyl-1H-benzimidazol-2-yl-κN 3)pyridine-κN]zinc dipicrate methanol disolvate
In the title compound, [Zn(C(21)H(17)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2CH(3)OH, the Zn(II) atom is coordinated by six N atoms from two tridentate 2,6-bis-(1-methyl-1H-benzimidazol-2-yl)pyridine ligands in a distorted octa-hedral environment. In the crystal, the picrate anions and methanol solvent mol-ecules are connected by O-H⋯O hydrogen bonds. Weak inter-molecular C-H⋯O hydrogen bonds are also ...
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